Red
On this page is information about red colours. These are:
- Vermilion Cinnabar
- Pink Madder / Rose Madder
- Light Red / Venetian Red
- Cochineal Lakes
- Red Lead
- Cadmium Red
- Litharge
- Realgar
Vermilion Cinnabar
Use - Paint pigment
Formula - HgS
Chemical Name - Mercuric sulfide
Structure - Hexagonal
Synthesis - Mix mercury and sulfur until combined. Sublime and condense. Powder, grind and moisten the product with water, followed by warm water containing nitric acid.
Interesting Facts - Used in the wall paintings of Pompeii.
Pink Madder / Rose Madder
Use - Paint pigment
Formula - n/a
Chemical Name - n/a
Structure - n/a
Synthesis - Manufactured from anthrocene found in cool tar.
Interesting Facts - Was used in the 14th century, when it was made from the root of the madder plant native to Greece. The root was dried, ground and treated with sulfuric acid, filtered and washed with water.
Light Red / Venetian Red
Use - Paint pigment
Formula - Fe2O3
Chemical Name - Iron(III) oxide
Structure - Rhombohedral
Synthesis - Heat yellow ochre (iron(III) oxide monohydrate) to drive off its associated water. Alternatively grind the red hematite mineral.
Interesting Facts - Used in cave paintings as well as by the Egyptians, Ancient Greeks and Romans.
Cochineal Lakes
Use - Paint pigment
Formula - n/a
Chemical Name - n/a
Structure - n/a
Synthesis - Grind dried Cochineal beetles, boil in water for several weeks and treat with dilute sulfuric acid.
Interesting Facts - Was used as a food colouring since Victorian times. Made from dry, wingless female Cochineal beetles. Carminic acid gives the red colour and is hyrolysed by dilute sulfuric acid to give armine red and sugar. It was colour additive E120. In the pictures the far right depicts dried cochineal beetles, and the near right depicts modern synthetic carmine.
Red Lead
Use - Paint pigment
Formula - Pb3O4 or 2PbO • PbO2
Chemical Name - Lead tetraoxide / lead(II,II) oxide
Structure - Tetragonal
Synthesis - Heat lead oxide in a furnace in air.
Interesting Facts - Toxic because it is soluble in hydrochloric acid found in the stomach.
Cadmium Red
Use - Paint pigment
Formula - CdSe
Chemical Name - Cadmium selenide
Structure - n/a
Synthesis - n/a
Interesting Facts - n/a
Litharge
Use - Paint pigment
Formula - PbO
Chemical Name - Tetragonal lead(II) oxide
Structure - Tetragonal
Synthesis - Naturally occuring mineral.
Interesting Facts - n/a
Realgar
Use - Paint pigment
Formula - As2S3
Chemical Name - Red arsenic sulfide
Structure - Monoclinic
Synthesis - Heat realgar mineral with sulfur.
Interesting Facts - Realgar mineral highly toxic.